Diels-Alder reactions of vinylboranes: a computational study on the boron substituent effects
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چکیده
The effect of substitution on boron in the Diels-Alder reactions of vinylboranes has been investigated by a computational study performed with the B3LYP/6-31G* method. Four vinylboranes with different electronic and steric properties were chosen to study the reactivity and the regioand stereoselectivities patterns. In general, the calculations for the reactions with cyclopentadiene, trans-piperylene and isoprene are in good agreement with experimental results.
منابع مشابه
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تاریخ انتشار 2007